The CW has released the first official photo from Supernatural Season 9, which debuts October 8 on its new night, moving from Fridays to Tuesdays. Sam (Jared Padalecki) and Dean (Jensen Ackles) Winchester must deal with the fallen angels of heaven as Castiel (Misha Collins) ditches his trademark trench coat for a suit on his way to becoming fully human in all-new episodes of Supernatural this fall.